Structure
| TCI Product No. : | T1909 | ||||||||||||||
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| Stock Status : |
Status at 03:00 a.m. on 08 Feb 2012 * Items available from stock in Japan will be delivered in 10 business days |
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| Purity / Analysis Method : | >97.0%(T) | ||||||||||||||
| Storage : | |||||||||||||||
| M.F. / M.W. : | C34H51F2NSi=539.87 | ||||||||||||||
| CAS Number : | 163931-61-1 | ||||||||||||||
| Related CAS Number : | |||||||||||||||
| MDL Number : | MFCD00274218 | ||||||||||||||
| mp : | 156 °C |
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Insertion of Benzene Rings into the Amide Bond Typical Procedure: To a solution of the amide (0.250 mmol) and TBAT (0.500 mmol) in toluene (3 mL) is added the benzyne precursor (0.375 mmol). The reaction is heated at 50℃ for 16 h and concentrated under reduced pressure. The resulting mixture is purified by flash chromatography on silica gel (dry loading) to afford the desired product. Nucleophilic Fluorination
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| UNNo. : | 3261 |
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| Class : | 8 |
| PG : | II |
| Signal Word : | Danger |
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| Pictogram : |
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| GHS H Statement : | May be corrosive to metals. Causes severe skin burns and eye damage. |
| GHS P Statement : | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Do not breathe. Wear protective gloves/eye protection/face protection. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. |
| R34 : | Causes burns. |
| S24/25 : | Avoid contact with skin and eyes. |
| S36 : | Wear suitable protective clothing. |
| TCI MAIL : | |
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| TCI Product Literature : | |
| Related Categories : |
Structure of Chemicals
Si (Classes of Silicon Compounds)
Si-X (F, Br, I) Compounds
Synthetic Organic Chemistry Fluorinating Reagents, Building Blocks & Fluorinated Bioactive Compounds Fluorinating Reagents Nucleophilic Fluorinating Reagents Synthetic Organic Chemistry Halogenation Fluorination Structure of Chemicals Quaternary Ammonium Compounds Ammonium Polyhalides, etc. (Quaternary) |