No.139
Alkyne Cross Metathesis Reaction
| T2358 | Tris(N-tert-butyl-3,5-dimethylanilino)molybdenum(III) (1) |
100mg |
Tris(N-tert-butyl-3,5-dimethylanilino)molybdenum(III) (1) is a three-coordinate molybdenum(III) complex developed by Cummins et al. The said compound 1, reacts with dinitrogen to give the corresponding nitridomolybdenum complex. Fürstner et al. have reported alkyne metathesis reactions using 1 as a catalyst. Since these reactions proceed under mild conditions and the protocol permits the use of various functionalized alkynes, 1 has attracted much attention.
References
1) Three-coordinate molybdenum(III) complex
C. C. Cummins, Chem. Commun. 1998, 1777[DOI].
2) Alkyne cross metathesis reactions
A. Fürstner, C. Mathes, Org. Lett. 2001, 3, 221[DOI].
C. C. Cummins, Chem. Commun. 1998, 1777[DOI].
2) Alkyne cross metathesis reactions
A. Fürstner, C. Mathes, Org. Lett. 2001, 3, 221[DOI].
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